Determination of dimethoate pesticide residues in water in the environment surrounding Lake Al-Sin
الكلمات المفتاحية:
Keywords: Organophosphate pesticides, Dimetoate, Al Sin spring basin, soil, HPLC
الملخص
The research aimed to determine the concentration of the synthetic organophosphorous pesticide Dimethoate in the soils of the environment surrounding Lake Al-Sin during the extended period from December 2020 to June 2021. Soil samples were taken from two sites, one citrus and the other greenhouse. The study continued for seven consecutive months, the soil texture was determined and the organic matter was determined seasonally, and the pH - electric conductivity (EC), PO43- and humidity were measured. The herbicide analysis was carried out using high performance liquid chromatography (HPLC). The results showed the presence of dimethoate residues in the studied soil samples, with concentrations ranging between (4-34) mg.kg-1, and thus soil contamination with dimethoate was observed in the soil, and the highest concentrations were found in the greenhouse installation, as a result of the intensive use of dimethoate.
References
المراجع العربية:
الأزكي، فواز. عبد الكريم العبد الله. (2013). دراسة العلاقة بين هيدرولوجية حوض السن وتكتونيتها. مجلة جامعة تشرين للبحوث والدراسات العلمية. سلسلة العلوم الأساسية 35 (4)، 55-75.
رزوقي، سراب محمد؛ الراوي، محمد عمار. (2010). دراسة مقارنة حول سلامة إمدادات مياه الشرب في مدينة بغداد. المجلة العراقية لبحوث السوق وحماية المستهلك، المجلد(2) العدد(4)، 98-129.
شريف، نعمى. (2000). تحديد مخطط لمياه نبع السن بالعلاقة مع الظروف الهيدرولوجية ومجالات استخدامها. رسالة ماجستير. قسم الهندسة البيئية، كلية الهندسة المدنية، جامعة تشرين: سورية.
صقر، إبراهيم. (2001). مكافحة الآفات (الجزء النظري). منشورات جامعة تشرين، اللاذقية-سوريا،269 ص.
علي، ضياء. تحديد الأثر المتبقي لبعض المبيدات الفوسفورية العضوية في ترب الزراعات المحمية حالة الدراسة: برج اسلام -محافظة اللاذقية. قسم الكيمياء البيئية-المعهد العالي لبحوث البيئة، جامعة تشرين: سورية، 2020. 80 ص.
عيسى، مريم. (2015). هيدرولوجية حوض نهر السن وإدارة الموارد المائية فيه. مجلة جامعة دمشق. 31(1+2)، 605-638.
References:
Bastien, Charlotte , 1991. Pesticide Levels in Agricultural Drainage Systems in Quebec (Master). Mcgill University, Montreal, Quebec, Canada.
Binhui, J., Chanqi, Y., Hengpeng, W., Kunyu, G., Bin, L., Li, J., Rui, H., Wei, P. (2011). Study on Relationship between Microbial Diversity and Organophosphate Pesticide Residues in Planting Base Soils of Shenyang. Fourth International Conference on Intelligent Computation Technology and Automation. Presented at the 2011 Fourth International Conference on Intelligent Computation Technology and Automation, pp. 878–881.
Bouyoucos, George John. (1962). Hydrometer Method Improved for Making Particle Size Analyses of Soils. Agron. J. 54, 464–465.
Bratoev et al., 2020, K., Beloev, H., Mitkov, A., Mitev, G., 2020. On the possibility of conducting fast and reliable soil tests. Mechanization in agriculture & Conserving of the resources 66, 71–76.
Brevik, E.C., Fenton, T.E., 2002. The relative influence of soil water, clay, temperature, and carbonate minerals on soil electrical conductivity readings taken with an EM-38 along a Mollisol catena in central Iowa. Soil Survey, Horizons 43, 9–13
Broznic, D., Didovic,M. P., Rimac,V and Marinic, j. (2021). Sorption and leaching potential of organophosphorus insecticide dimethoate in Croatian agricultural soils. Chemosphere, 273: 128563.
Conyers, M.K. and B.G. Davey. 1988. Observations on some routine methods for soil pH determination. Soil Science, 145: 29-36.
Dehghani, R., , M., Esalmi, H., Moosavi, S.G., Khah Rabani, D., Hossein Shahi, D. (2012). Detrmination Shayeghi of Organophosphorus Pesticides (Diazinon and Chlorpyrifos) in Water Resources in Barzok, Kashan. Zahedan J. Res. Med. Sci. 14, 66–72.
de Jonge, H., Wollesen de Jonge, L., 1999. Influence of pH and solution composition on the sorption of glyphosate and prochloraz to a sandy loam soil. Chemosphere 39, 753–763.
Deshpande, N., Sarnaik, S.S., Paranjpe, S., Kanekar, P. (2004). Optimization of Dimethoate Degradation by Brevundimonas sp. MCM B-427 Using Factorial Design: Studies on Interactive Effects of Environmental Factors. World J. Microbiol. Biotechnol. 20, 455–462.
FAO 2012 Specifications and Evaluations for Agricultural Pesticides Dimethoate, CGA, 184927, 0230.
Ferreira, JA, Nascimento, OR, Martin-Neto, L. (2001). Hydrophobic interactions between spin-label 5-SASL and humic acid as revealed by ESR spectroscopy. Environ Sci Technol 35:761–765.
Guleria, S. jaggi, Shanker, A., Singh, B., 2022. Determination of Deltamethrin & Dimethoate in Tea Soil. International Journal for Scientific Research & Development|, 2021 | ISSN (online): 2321-0613 Vol. 9, 132–137. https://doi.org/10.5281/zenodo.6576238
Joko, T., Anggoro, S., Sunoko, H.R., Rachmawati, S. (2018). Identification of Soil Properties and Organophosphate Residues From Agricultural Land in Wanasari Sub-District, Brebes, Indonesia. E3S Web Conf. 31, 06010.
Kah, Melanie and Brown, Colin. (2006). Adsorption of Ionisable Pesticides in Soils. Reviews of environmental contamination and toxicology. Rev Environ Contam Toxicol 188:149–217.
Kachi, N., Kachi, S., Houria, K. (2016). Effects of Irrigated Agriculture on Water
and Soil Quality (Case Perimeter Guelma, Algeria). Soil Water Res. 11,(2) 97–104.
Kaushik, Ekta. (2017). Persistence of Dimethoate, Malathion
and Tetraniliprole in Tomato. Department of Entomology, Uttarakhand University of Horticulture & Forestry (UUHF), India.
Korimort, N., Blum, W., Sieghardt, M., Lesueur, C., Mentler, A. (2012). A preliminary study of the content and distribution of pesticide residues in soil samples from the Kathmandu valley, Nepal. Span. J. Soil Sci. 2, 20–31.
Linde, C.D., 1994. Physico-chemical Properties and Environmental Fate of Pesticides. Environmental Hazards Assessment Program, State of California, Environmental Protection Agency, Department of Pesticide Regulation, Environmental Monitoring and Pest Management Branch.
Loria, N., Verma, K., Bhardwaj, S.K., Brahmi, M., 2015. Impact of catchment land use on water quality of Pong Wetland of Himachal Pradesh. Indian Journal of Ecology 42, 21–26.
Loria, N., Bhardwaj, S., Ndungu, C., 2016. Impact of cropping systems on soil properties, nutrient availability and their carbon sequestration potential in Shiwalik hills of Himachal Pradesh. Journal of Applied and Natural Science 8, 1479–1484. https://doi.org/10.31018/jans.v8i3.987
Martikainen, E., 1996. Toxicity of Dimethoate to Some Soil Animal Species in Different Soil Types. Ecotoxicology and Environmental Safety 33, 128–136.
Pan, L., Sun, J., Li, Z., Zhan, Y., Xu, S., Zhu, L. (2018). Organophosphate pesticide in agricultural soils from the Yangtze River Delta of China: concentration, distribution, and risk assessment. Environ. Sci. Pollut. Res. 25.
Pehkonen, S., Zhang, Q., 2002. The Degradation of Organophosphorus Pesticides in Natural Waters: A Critical Review. Critical Reviews in Environmental Science and Technology – Crit Rev Environ Sci Technol 32, 17–72. https://doi.org/10.1080/10643380290813444
Public Health Statement, Divhlorvos. (1997). Department of Health and Human Services, Public Health Service.
PPDB (2014) The pesticide properties database. Accessed 10 Aug 2014.
Rani, S., Sud, D., 2022. Degradation of Dimethoate Pesticide in Soil: Impact of Soil Moisture and Enhanced Sunlight Intensity. Water Air Soil Pollut 233, 24.
Regitano, J.B., Bischoff, M., Lee, L.S., Reichert, J.M., Turco, R.F., 1997. Retention of imazaquin in soil. Environmental Toxicology and Chemistry 16, 397–404.
Scoy, A. V., Pennell, A., & Zhang, X.. Environmental fate and toxicology of dimethoate. Reviews of Environmental Contamination and Toxicology. 2016, Volume 237, 53-70.
Sommer, Rolf., George, Estefan., Ryan, John. (2013). Methods of soil, plant, and water analysis." A manual for the West Asia and North Africa, region 3. ed.
Stroh, J.C., Archer, S.R., Doolittle, J.A., Wilding, L.P., 2001. Detection of edaphic discontinuities with groundpenetrating radar and electromagnetic induction. Landscape Ecol. 16 (5), 377– 390.
Vagi, M.C., Petsas, A.S., Kostopoulou, M.N., Lekkas, T.D. (2010). Adsorption and desorption processes of the organophosphorus pesticides, dimethoate and fenthion, onto three Greek agricultural soils. Int. J. Environ. Anal. Chem. 90, 369–389.
Walkley, A. and A. Black. (1934). An examination of the Degtjareff method for determining soil organic matter and a proposed modification of the chromic acid titration method. Soil Sci., 37: 29–38.
Wee, S.Y., Omar, T.F.T., Aris, A.Z., Lee, Y. (2016). Surface Water Organophosphorus Pesticides Concentration and Distribution in the Langat River, Selangor, Malaysia. . 8:497–51
الأزكي، فواز. عبد الكريم العبد الله. (2013). دراسة العلاقة بين هيدرولوجية حوض السن وتكتونيتها. مجلة جامعة تشرين للبحوث والدراسات العلمية. سلسلة العلوم الأساسية 35 (4)، 55-75.
رزوقي، سراب محمد؛ الراوي، محمد عمار. (2010). دراسة مقارنة حول سلامة إمدادات مياه الشرب في مدينة بغداد. المجلة العراقية لبحوث السوق وحماية المستهلك، المجلد(2) العدد(4)، 98-129.
شريف، نعمى. (2000). تحديد مخطط لمياه نبع السن بالعلاقة مع الظروف الهيدرولوجية ومجالات استخدامها. رسالة ماجستير. قسم الهندسة البيئية، كلية الهندسة المدنية، جامعة تشرين: سورية.
صقر، إبراهيم. (2001). مكافحة الآفات (الجزء النظري). منشورات جامعة تشرين، اللاذقية-سوريا،269 ص.
علي، ضياء. تحديد الأثر المتبقي لبعض المبيدات الفوسفورية العضوية في ترب الزراعات المحمية حالة الدراسة: برج اسلام -محافظة اللاذقية. قسم الكيمياء البيئية-المعهد العالي لبحوث البيئة، جامعة تشرين: سورية، 2020. 80 ص.
عيسى، مريم. (2015). هيدرولوجية حوض نهر السن وإدارة الموارد المائية فيه. مجلة جامعة دمشق. 31(1+2)، 605-638.
References:
Bastien, Charlotte , 1991. Pesticide Levels in Agricultural Drainage Systems in Quebec (Master). Mcgill University, Montreal, Quebec, Canada.
Binhui, J., Chanqi, Y., Hengpeng, W., Kunyu, G., Bin, L., Li, J., Rui, H., Wei, P. (2011). Study on Relationship between Microbial Diversity and Organophosphate Pesticide Residues in Planting Base Soils of Shenyang. Fourth International Conference on Intelligent Computation Technology and Automation. Presented at the 2011 Fourth International Conference on Intelligent Computation Technology and Automation, pp. 878–881.
Bouyoucos, George John. (1962). Hydrometer Method Improved for Making Particle Size Analyses of Soils. Agron. J. 54, 464–465.
Bratoev et al., 2020, K., Beloev, H., Mitkov, A., Mitev, G., 2020. On the possibility of conducting fast and reliable soil tests. Mechanization in agriculture & Conserving of the resources 66, 71–76.
Brevik, E.C., Fenton, T.E., 2002. The relative influence of soil water, clay, temperature, and carbonate minerals on soil electrical conductivity readings taken with an EM-38 along a Mollisol catena in central Iowa. Soil Survey, Horizons 43, 9–13
Broznic, D., Didovic,M. P., Rimac,V and Marinic, j. (2021). Sorption and leaching potential of organophosphorus insecticide dimethoate in Croatian agricultural soils. Chemosphere, 273: 128563.
Conyers, M.K. and B.G. Davey. 1988. Observations on some routine methods for soil pH determination. Soil Science, 145: 29-36.
Dehghani, R., , M., Esalmi, H., Moosavi, S.G., Khah Rabani, D., Hossein Shahi, D. (2012). Detrmination Shayeghi of Organophosphorus Pesticides (Diazinon and Chlorpyrifos) in Water Resources in Barzok, Kashan. Zahedan J. Res. Med. Sci. 14, 66–72.
de Jonge, H., Wollesen de Jonge, L., 1999. Influence of pH and solution composition on the sorption of glyphosate and prochloraz to a sandy loam soil. Chemosphere 39, 753–763.
Deshpande, N., Sarnaik, S.S., Paranjpe, S., Kanekar, P. (2004). Optimization of Dimethoate Degradation by Brevundimonas sp. MCM B-427 Using Factorial Design: Studies on Interactive Effects of Environmental Factors. World J. Microbiol. Biotechnol. 20, 455–462.
FAO 2012 Specifications and Evaluations for Agricultural Pesticides Dimethoate, CGA, 184927, 0230.
Ferreira, JA, Nascimento, OR, Martin-Neto, L. (2001). Hydrophobic interactions between spin-label 5-SASL and humic acid as revealed by ESR spectroscopy. Environ Sci Technol 35:761–765.
Guleria, S. jaggi, Shanker, A., Singh, B., 2022. Determination of Deltamethrin & Dimethoate in Tea Soil. International Journal for Scientific Research & Development|, 2021 | ISSN (online): 2321-0613 Vol. 9, 132–137. https://doi.org/10.5281/zenodo.6576238
Joko, T., Anggoro, S., Sunoko, H.R., Rachmawati, S. (2018). Identification of Soil Properties and Organophosphate Residues From Agricultural Land in Wanasari Sub-District, Brebes, Indonesia. E3S Web Conf. 31, 06010.
Kah, Melanie and Brown, Colin. (2006). Adsorption of Ionisable Pesticides in Soils. Reviews of environmental contamination and toxicology. Rev Environ Contam Toxicol 188:149–217.
Kachi, N., Kachi, S., Houria, K. (2016). Effects of Irrigated Agriculture on Water
and Soil Quality (Case Perimeter Guelma, Algeria). Soil Water Res. 11,(2) 97–104.
Kaushik, Ekta. (2017). Persistence of Dimethoate, Malathion
and Tetraniliprole in Tomato. Department of Entomology, Uttarakhand University of Horticulture & Forestry (UUHF), India.
Korimort, N., Blum, W., Sieghardt, M., Lesueur, C., Mentler, A. (2012). A preliminary study of the content and distribution of pesticide residues in soil samples from the Kathmandu valley, Nepal. Span. J. Soil Sci. 2, 20–31.
Linde, C.D., 1994. Physico-chemical Properties and Environmental Fate of Pesticides. Environmental Hazards Assessment Program, State of California, Environmental Protection Agency, Department of Pesticide Regulation, Environmental Monitoring and Pest Management Branch.
Loria, N., Verma, K., Bhardwaj, S.K., Brahmi, M., 2015. Impact of catchment land use on water quality of Pong Wetland of Himachal Pradesh. Indian Journal of Ecology 42, 21–26.
Loria, N., Bhardwaj, S., Ndungu, C., 2016. Impact of cropping systems on soil properties, nutrient availability and their carbon sequestration potential in Shiwalik hills of Himachal Pradesh. Journal of Applied and Natural Science 8, 1479–1484. https://doi.org/10.31018/jans.v8i3.987
Martikainen, E., 1996. Toxicity of Dimethoate to Some Soil Animal Species in Different Soil Types. Ecotoxicology and Environmental Safety 33, 128–136.
Pan, L., Sun, J., Li, Z., Zhan, Y., Xu, S., Zhu, L. (2018). Organophosphate pesticide in agricultural soils from the Yangtze River Delta of China: concentration, distribution, and risk assessment. Environ. Sci. Pollut. Res. 25.
Pehkonen, S., Zhang, Q., 2002. The Degradation of Organophosphorus Pesticides in Natural Waters: A Critical Review. Critical Reviews in Environmental Science and Technology – Crit Rev Environ Sci Technol 32, 17–72. https://doi.org/10.1080/10643380290813444
Public Health Statement, Divhlorvos. (1997). Department of Health and Human Services, Public Health Service.
PPDB (2014) The pesticide properties database. Accessed 10 Aug 2014.
Rani, S., Sud, D., 2022. Degradation of Dimethoate Pesticide in Soil: Impact of Soil Moisture and Enhanced Sunlight Intensity. Water Air Soil Pollut 233, 24.
Regitano, J.B., Bischoff, M., Lee, L.S., Reichert, J.M., Turco, R.F., 1997. Retention of imazaquin in soil. Environmental Toxicology and Chemistry 16, 397–404.
Scoy, A. V., Pennell, A., & Zhang, X.. Environmental fate and toxicology of dimethoate. Reviews of Environmental Contamination and Toxicology. 2016, Volume 237, 53-70.
Sommer, Rolf., George, Estefan., Ryan, John. (2013). Methods of soil, plant, and water analysis." A manual for the West Asia and North Africa, region 3. ed.
Stroh, J.C., Archer, S.R., Doolittle, J.A., Wilding, L.P., 2001. Detection of edaphic discontinuities with groundpenetrating radar and electromagnetic induction. Landscape Ecol. 16 (5), 377– 390.
Vagi, M.C., Petsas, A.S., Kostopoulou, M.N., Lekkas, T.D. (2010). Adsorption and desorption processes of the organophosphorus pesticides, dimethoate and fenthion, onto three Greek agricultural soils. Int. J. Environ. Anal. Chem. 90, 369–389.
Walkley, A. and A. Black. (1934). An examination of the Degtjareff method for determining soil organic matter and a proposed modification of the chromic acid titration method. Soil Sci., 37: 29–38.
Wee, S.Y., Omar, T.F.T., Aris, A.Z., Lee, Y. (2016). Surface Water Organophosphorus Pesticides Concentration and Distribution in the Langat River, Selangor, Malaysia. . 8:497–51
منشور
2024-02-25
How to Cite
Okdeh, deema, Ibrahim Saqr, & Tariq Araj. (2024). Determination of dimethoate pesticide residues in water in the environment surrounding Lake Al-Sin. Journal of Hama University , 6(12). Retrieved from https://hama-univ.edu.sy/ojs/index.php/huj/article/view/1472
القسم
Department of Sciences
